Use clauses in commercial leases do carry more weight than residential lease terms, but you are right that enforcement is rarely clean even when the language is solid.
Here is how it tends to play out. The lease says something like "light assembly of wood cabinet products only." Powder coating is a different process entirely. It involves chemicals, exhaust, and often zoning implications or environmental permits that the landlord never signed up for. So the landlord has a legitimate breach to point to, and in commercial leases, breach of a use clause is typically a default event, meaning the landlord can issue a cure notice and, if the tenant does not comply, begin termination proceedings. That is a real lever, not just a paper threat.
The practical complication is exactly what you suspected. If the tenant is paying rent on time, most landlords do not want to start a fight that risks a vacancy. So what actually happens is often a negotiation: the landlord either says stop or we amend, or the tenant volunteers an amendment request because they know they need one. Amendments cost money, sometimes rent bumps or tenant-paid legal fees, and that is where the landlord recovers something for the added use.
The thing worth knowing here is the environmental angle. Powder coating can trigger hazardous material storage rules, insurance policy exclusions, and local zoning requirements that are completely separate from the lease. A tenant breach that creates an environmental liability is a much harder situation than a tenant breach that is just about noise or hours. A real estate attorney familiar with commercial leases in your state should review any use clause before you close on a building like this, and an environmental consultant can tell you what a given industrial use actually triggers.
What does the use clause language look like on the deal you are walking right now?